Study New BMB 401H Chap 11 Flash Cards

 
Pile Management Card
New BMB 401H Chap 11

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cellibiose
glucose and glucose
b
maltose
glucose and glucose
a
sucrose
glucose and fructose
a
hemiacetal
-alcohol + aldehyde
penicillin
-penicillin binds and inactivates enzymes that crosslink peptidoglycan strands
-interferes w/ cell wall synthesis
peptidoglycan layer
-N-acetylglucosamine and N-acetylmuramic acid
-pentaglycine linkages
bacterial cell wall
-need for fast osmotic changes
glycogen phosphorylase
-cleaves off glucose units from non-reducing end
pancreatic amylase
-continues digestion to maltose and maltotriose
branching
-only 1 reducing end in glycogen
-can be oxidized to free aldehyde
glucosidase
-removes one glucose at a time
amylase
-in saliva
-catalyzes random cleavages
starch
-we can eat
-composed of amylose and amylopectin
-alpha 1-4 bonds
-so we can eat it!
-accessible to hydrolytic anzymes (amylase in saliva)
chitin
-exoskeletons
-B linked
cellulose
-B linked
-structural component in plants
-glycosidic bonds
maltose
-alpha linked
-we can digest
cellibiose
-beta linked
-we can't digest
galacans
-polymer of galactose
glucans
-ploymer of glucose
glycan
-polysaccharide
-linked by glycosidic bonds
uronic acids
-tendency to form internal esters yielding lactones
glycosidases
-catalyze hydrolysis of bonds
glycosidic bond
-peptide bond of carbs
chair and boat
-chair or boat
-2 chair cnoformations depending on whether axial or equatorial
mutarotation
-formation of anomeric carbon changes rotation of polarized light
anomeric carbon
-alpha or beta anomers
-beta= balanced
epimers
-2 sugars that differ in configuration by only 1 chiral carbon
diastereomers
-2 chiral carbons that are not mirror images
enantiomers
-stereoisomers that are mirror images
glycoconjugates
-glycolipids and glycoproteins
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